Here's a flicker between sol 21 and 24 showing change (or, rather, lack of):
http://i108.photobucket.com/albums/n15/ugordan/sol21_24_flickr.gif
Ignore the color of the brightest part of the white stuff, it's overexposed. The small white chunk in sol 21 image appears to disappear in sol 24 (inset).
Yes, that one. It's in the shadow in sol 24 image, but other darker bits are subtly visible and yet this one isn't.
Nice animation!
There is another tiny chunk in the far right of the images (below the furthest right white streak) that is in full sunlight in both images that went away in the second image of the sequence.
-Mike
Here's my take on the sol 20 - sol 24 changes using the 5 filter (R1ABC2) set from each for comparison. Ugordon's warnings about the brightest features absolutely apply. There might be legitimate changes, but they might also just be overexposure / time-of-day / stretching differences.
The "bright stuff" under the shadow I feel much more confident about: it's there on sol 20, gone by sol 24.
http://www.lyle.org/~markoff/collections/dodo20_24comp_R1ABC2.gif
good point to obserwation is in this place also
http://www.flickr.com/photos/hortonheardawho/2592881091/sizes/o/
Beautiful stuff, guys. I agree about the disappearing light bits in the shadow. But the lighting in the latest gifs (slinted, horton) is very similar on sols 20 and 24, as you can see by the shadows. We are again clearly seeing a darkening over time of the larger exposed substrate areas.
How does this sound: White substrate is mostly white ice, plus some dark dust/sand impurities. As the ice sublimates, the impurities are left behind. Eventually, the surface of the substrate is essentially completely covered by the dark impurities. That stage has almost been reached on the leftmost large exposed substrate area - there's very little white left by sol 24.
Awesome animation, slinted. That went straight to the blog.
--Emily
slinted and all...
awesome indeed ... Peter Smith agrees...
http://phoenix.lpl.arizona.edu/06_19_pr.php
MUST BE ICE!!!!
Craig
So as far as those disappearing chunks, how did they sublimate so fast? I thought we were talking microns per day of sublimation...
That was for ice attached to a large body. A relatively small piece sitting on regolith would behave quite differently.
It also crosses my mind that those "chunks" might be more like shavings than solid blocks.
I so could not resist this!
http://www.youtube.com/watch?v=Vp-is6S_b_g
EDIT: poignant lyric for today:
"If there was a problem yo I'll solve it
Check out the hook while my DJ revolves it "
http://phoenix.lpl.arizona.edu/
NASA and the University of Arizona, Tucson, will hold a media teleconference at 10 a.m. PDT (1 p.m. EDT) (5 p.m. UTC) on Friday, June 20, to report on the latest news from NASA's Phoenix Mars Lander mission.
I wonder what the major topic will be?
Jack
Note This conference is only posted on the Arizona web page as of 11:00 p.m. EDT. I hope it will be announced on NASA's audio streaming page soon
http://www.nasa.gov/news/media/newsaudio/index.html
http://www.nasa.gov/news/media/newsaudio/index.htm
Whoa! I've just read an AP summary of the press conference in which it is stated that, yes, it IS ice under the thin, insulating layer of Martian dust. And I'm going to go out on a limb and agree with the exogeologists who have been surmising that this is not just a polar region phenomenon, but global, ie, Mars may have as much water. relatively speaking, as Earth, only it is locked away as ice under a relatively thin layer of Martian regolith. And thus volcanic activity can unleash the torrents of water in evidence all over the planet. And this perhaps also accounts for the "seepages" that we see in the sides of many craters. And thus it is likely as well that there are pockets -- perhaps huge pockets -- of liquid water at many, many places under the surface.
Ice on Mars! Now you see it, now you don’t
Scientists say they know white stuff was frozen water because it vanished
http://www.msnbc.msn.com/id/25274243/
The http://news.yahoo.com/s/ap/20080620/ap_on_sc/phoenix_mars had at least one quote that was copied verbatim from the press release; the press conference hasn't happened yet. It does contain some news from Barry Goldstein saying that they now understand the sol 22 anomaly and have developed a software patch. Glennwsmith, there probably is lots of ice underneath the surface but it is not as close to the surface elsewhere on Mars (where it is warmer) as it is near the poles.
I hope to be able to listen in to tomorrow's press conference but I've got the baby on Fridays and I don't know what her plans are for me yet...
--Emily
How do we know this is water and not CO2 ice already? We all suspect this of course but the media is reporting it as fact. TEGA hasn't found any water yet so is there some IR spectral measurement I don't know about?
Too low pressure and high temperature for CO2 ice. We know the temperature at the landing site -- on sol 22, for instance, it was a high of -22 and a low of -80. And the pressure is very low, on the order of 8 millibars. If you look at a phase diagram for carbon dioxide, you'll see it's always a gas under all these conditions -- it has to get really, really cold to make carbon dioxide ice, and you don't get that cold at the low elevations near Mars' north pole during the summer.
m! case closed. forgot about the relatively high temps right now at the landing site.
Water being stable as a solid at 8 millibars as indicated on a phase diagram would require a partial pressure of water vapor of 8 millibar not a total atmospheric pressure of 8 millibar. A layer of dirt on top of the ice could prevent the water vapor sublimated from the ice from diffusing away to the atmosphere so the vapor pressure of water vapor below the soil could remain near atmospheric pressure. Removing the dirt layer protecting it would allow the water vapor to disperse. Then the ice would then be exposed the the atmosphere which is mostly CO2 with little water vapor. Ice at the surface would be unstable and would sublimate unless the temperature was low enough to be at equilibrium with the partial pressure of water vapor in the atmosphere.
Not to toss out the water too soon, but ....
There is also the possibility that this loss of bright stuff in the trenches could be water of hydration evaporating from a salt newly exposed to the open dry atmosphere. (water of hydration of a salt is NOT ice.) This would change the crystal morphology of the salt. This would then be expected to change the brightness/reflectivity of the salts. Frankly, I am surprised to see that everyone is proclaiming this ice without eliminating this possibility.
For example, magnesium sulfate exists as MgSO4.7H2O. The waters of hydration are lost in a very dry atmosphere over about 3-4 days. The hydrated form is bright and crystalline and reflective. The annhydrous form is dull and non-reflective. I remember doing this experiment as a freshman in college!
I want to see analytical proof of water. I really do hope this is water !
p.s. I found this very nice paper, discussion exactly these phase transitions in mag sulfate under martian temperature/pressure conditions, and expected physical appearance: CONVERSION OF CRYSTALLINE MgSO4.XH2O TO THE HYDRATED AMORPHOUS PHASE – A
RAMAN, NIR, AND XRD STUDY. http://www.lpi.usra.edu/meetings/lpsc2006/pdf/2168.pdf
Evidence of water ice now being reported on CNN:
http://www.cnn.com/2008/TECH/space/06/20/phoenix.mars.ap/index.html
(I have a minor issue with this sentence in the article: "However, an initial soil sample heated in a science instrument failed to yield evidence of water". - Couldn't they have said "did not determine evidence for water" instead of using the f-word?)
-Mike
It's probably time to start looking for evidence of rust on the footpads...
Yeah, Phoenix' price as used hardware might be going down. Nothing a good paint job can't fix, though!
( briefly dropping out of lurking mode...)
As much as I hate to do so, I have to agree with silylene: the case for water-ice -- at least in the Goldilocks trench -- is "not proven".
http://www.flickr.com/photos/hortonheardawho/2595680622/ is a sol 20-24 3D animation of the shadowed area in the trench.
I created it to see if I could see how much of the clumps remained after the "sublimation". Unfortunately even the NASA gif image drops out in the darkest part of the shadow -- where the most interesting clumps were. But if you look closely at the bright clumps that fade nearest the shadow edges I think you can see that the clumps do not completely disappear.
Even in the darkest shadow there appears to be "something" where the white clumps were -- so, yes, there may have been a dramatic change in the white clumps -- but perhaps no more so than the reductiion in the brightness parts of the top of the trench.
Yeah, I believe that it's water-ice but it's not yet scientifically proven.
I am still puzzled why the infrared spectrum from the left SSI camera has not been cited as supporting evidence for water-ice.
( jumping back into cyber-space...)
http://www.nasa.gov/news/media/newsaudio/index.html on right now...
Big day for Mark and the rest of the team. Congratulations!
Well the whole world knows now about the water ice
It's the main headline on the Drudge Report website
points to a Bloomberg article:
http://www.bloomberg.com/apps/news?pid=20601087&sid=aI10wpl35qqY&refer=worldwide
Man, I really think this discovery, or rather confirmation, demands a new thread, something entitled "it IS ice"... Done - J
We now know for sure that Mars is full of rocket fuel and water to drink. Fantastic news.
Thanks, Gordan! Had to miss the telecon; I'm in Texas attending a work-related class.
I would be curious to know just how rapidly suitably small ice crystals would sublimate during the daytime at the site, though. Presumably the team has a model for this; they'd need it to estimate the actual water content of the sample prior to acquisition.
BTW have we had a look at Snow Queen lately? Ten bucks and my left (elbow) says it is going to sublimate away, albeit slower than the fresh samples.
The feature reminds me of those dirty ice chunks that build up under the wheel wells of a car and then drop on the street.
Been wondering about that myself, actually; it's been awhile, but guess that the arm's been a bit busy. Seems like an important observation, though.
Re car wheelwell ice chunks, here's a quick story. When I first read about meteorites when I was little in the middle of a Montana winter there were apparently all kinds of things that looked like them on the road- black, sooty torn up 'rocks'. Spent an entire afternoon collecting & dragging these things into my backyard, convinced that I was doing important sample collection...my parents were a bit displeased later on after discovering a sizeable mound of crappy road ice back there!
Um, I was not a particularly bright kid...
A number that's relevant to this discussion is what the maximum mass capability of the mass spec in TEGA is -- I can't seem to get that to turn up on a quick Google search. My guess is that amino acids are too large to be detectable -- that they're looking for smaller stuff, simpler carbon chains -- but that's just a guess, and it'd be helpful if someone could turn up a reference on this. IIRC, the mass spec instrument on Cassini can only detect the very smallest amino acid, whichever one that is.
--Emily
Hmm. Thanks, Emily.
So, basically, the most wildly optimistic and hoped-for outcome would be to detect a plethora of simple products of thermal decomposition, which might hint at the existence of more complex molecules.
What are the design limitations of mass spectrometers with respect to identifying organics, anyhow? If I understand their operation correctly, they'll provide gross elemental composition with sort of a hint at relative abundances, but there's really no way to infer chemical structures except by comparison with standard "pure" spectra of a given substance.
Atomic mass limits for TEGA mass spectrometer:
"Phoenix Lander's Thermal Evolved Gas Analyzer: Differential Scanning Calorimeter and Mass Spectrometer Database Development
Author(s): Sutter, B.; Lauer, H. V.; Golden, D. C.; Ming, D. W.; Boynton, W. V.
Abstract: The Mars Scout Phoenix lander will land in the north polar region of Mars in May, 2008. One objective of the Phoenix lander is to search for evidence of past life in the form of molecular organics that may be preserved in the subsurface soil. The Thermal Evolved Gas Analyzer (TEGA) was developed to detect these organics by coupling a simultaneous differential thermal analyzer (SDTA) with a mass spectrometer. Martian soil will be heated to approx.1000 C and potential organic decomposition products such as CO2, CH4 etc. will be examined for with the MS. TEGA s SDTA will also assess the presence of endothermic and exothermic reactions that are characteristic of soil organics and minerals as the soil is heated. The MS in addition to detecting organic decompositon products, will also assess the levels of soil inorganic volatiles such as H2O, SO2, and CO2. Organic detection has a high priority for this mission; however, TEGA has the ability to provide valuable insight into the mineralogical composition of the soil. The overall goal of this work is to develop a TEGA database of minerals that will serve as a reference for the interpretation of Phoenix-TEGA. Previous databases for the ill-fated Mars Polar Lander (MPL)-TEGA instrument only went to 725 C. Furthermore, the MPL-TEGA could only detect CO2 and H2O while the Phoenix-TEGA MS can examine up to 144 atomic mass units. The higher temperature Phoenix-TEGA SDTA coupled with the more capable MS indicates that a higher temperature database is required for TEGA interpretation. The overall goal of this work is to develop a differential scanning calorimeter (DSC) database of minerals along with corresponding MS data of evolved gases that can used to interpret TEGA data during and after mission operations. While SDTA and DSC measurement techniques are slightly different (SDTA does not use a reference pan), the results are fundamentally similar and thus DSC is a useful technique in providing comparative data for the TEGA database. The objectives of this work is to conduct DSC and MS analysis up to 1000 C of select minerals that may be found in the martian soil. "
From NASA Technical Reports:
http://64.233.167.104/search?q=cache:QDVCYk7bkG8J:ntrs.nasa.gov/search.jsp%3FR%3D827370%26id%3D5%26qs%3DNe%253D25%2526Ns%253DArchiveName%25257C0%2526N%253D295%252B129+TEGA+MASS+SPECTROMETER+ATOMIC+WEIGHTS&hl=en&ct=clnk&cd=2&gl=us
Craig
Here is a link to a table of small organic molecules and their molecular weight (from Jovian/Titan-style atmosphere discharge experiment literature): (http://www.unmannedspaceflight.com/index.php?s=&showtopic=4003&view=findpost&p=91428)
With a detection limit of m.w. 144 (thanks, bellerapheron1!), the TEGA oven would be able to detect molecular weights that would get you up to aspartic acid (m.w. 133).
But remember, you'll only observe a peak at 133 amu. There are many combinations of atoms and structural configurations of those atoms that that could make the same peak. (As I learn everyday.)
(There are many ways to form amino acids, it doesn't necessarily infer life.)
-Mike
Microbes have survived on Earth for 90% of the planet's history despite all the climate change. Mars has had liquid oceans over long periods too.
They will easily be able to see bio-markers if they exist at this scale:
http://ares.jsc.nasa.gov/astrobiology/biomarkers/images.cfm
Long odds, but it's just possible these guys will be the first to see evidence of the Holy Grail they are after. And us too!
...and at meter scales could one look for such things like stromatolites?
The discriminant power of a mass spectrometer depends very much to its resolution. IIRC, A good lab MS on earth has a mass resolution of 1 in 10^5. On the other hand, INMS on Cassini had difficulty telling N2 from CO in the Enceladus plume. The actual molecular mass of N2 is 28.014 and of CO 28.010 (a difference of 1 in 7000). In addition, each element has different isotopes and based on their abundance, the mass peak splits to multiple peaks with difference in mass of approximately 1. Glycine has a molecular mass of 75. But even if TEGA shows a peak at 75, it is difficult to claim it is glycine, unless it can resolve all the peaks and the relative ratio of the peaks follows what is expected from the isotopic abundance of C, O and N on Mars.
If the soils have been heated up to 1000 oC, what is the chance that organic molecules with small enough MW will survive intact ?
Even if complex organics were there in the soil, it would be difficult to recognize their original structure by their low MW thermal degradation products.
And I concur that finding aminoacids in Mars would not be that ground shaking, these molecules are abundant ....
ok, back to watching Netherlands-Russia now :-)
...good one, Ted, but unlikely. Phoenix is in the North polar area...
So if there is significant subsurface ice on Mars, does that mean that there could also much more subsurface granite than has been detected so far on the surface?
Here are the only references to martian granite I found:
THEMIS detects blob of granite on Mars: http://themis.asu.edu/discoveries-granitepeaks
Ruthorford and Hess, LPS 7 (1981) abstracts 915-917. "Granite genesis in a planetary context: processes and important variables for Mars." http://articles.adsabs.harvard.edu/cgi-bin/nph-iarticle_query?1981LPI....12..915R&defaultprint=YES&filetype=.pdf
-Mike
I looked at some of the older images. I think there is already evidence of ice subliming away in the images from sols 20 and 21. The colour combination in following images is from slinted:
I can only sit back and marble at the collective wit here.
Brian
My sediments exactly.
We have now Doug to a new level.
Geology's 100 Greatest Puns will return after these messages....
I'll breccia anything we can't keep it going much longer, though...
-the other Doug
Will someone explain to akuo what happened to his post.
This thread's going to be slated.
I predict that these replies will work their way further and further towards the porphyry of geological nomenclature, before spiralling down into a serious syncline.
I'd love to ride across this land on a Horst and Graben a few rocks on the way.
sorry!
Of quartz.
I've never seen such twisted metamorphics in all my life. Is everybody on this thread...stoned?
(NOW I run like hell...)
Just confirmed: There is water on Mars: http://www.nasa.gov/mission_pages/phoenix/news/phoenix-20080731.html
I knew it when I saw the first pic of the"pond" ice was shown under the lander months ago
" LOS ANGELES - The Phoenix spacecraft has tasted Martian water for the first time. The robot heated up ice in one of its instruments earlier this week. Scientists say the chemical test confirms the presence of ice near the Martian north pole.
Until now, the evidence for ice has been circumstantial. That was based on photos Phoenix took of a hard splotchy area near its landing site and changes it saw in a trench."
http://news.yahoo.com/s/ap/20080731/ap_on_sc/phoenix_mars_2
(unnecessary chunk of previous post removed)
Loooong time lurker...first post...been wondering about this for a while....Has there been enough analysis done of the Martian "water" to make up a batch of it on Earth ??
Phoenix has "tasted" Martian water...what about us Earthlings ?? Is there eenough data on the water found on Mars to combine the appropriate elements (h2o +++ ??) and would it be safe for humans to actually sample ????
Does Martian Water have antioxidants and lycopene?
No, but it http://www.youtube.com/watch?v=jHElbD1imNo
Poison: $1
Antidote: $1 million
-the other Doug
...best business model ever, you two!
I suspect, though, that even faux Martian water would taste atrocious & smell worse, kinda like the tap water in Amarillo, Texas. If you leave a faucet dripping in that town for a week, you got yourself a sink stalagmite...
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