IPB
X   Site Message
(Message will auto close in 2 seconds)

Welcome Guest ( Log In | Register )

The Process of Tholin Formation in Titan's Upper Atmosphere, Science (May 11, 2007)
Guest_AlexBlackwell_*
post May 10 2007, 06:04 PM
Post #1





Guests






Hunter Waite et al. have a paper ("The Process of Tholin Formation in Titan's Upper Atmosphere") to be published in the May 11, 2007, issue of Science; there is also an accompanying Perspectives piece ("Titan's Organic Factory") by Sushil Atreya.

The embargo will be lifted in a hour or two, so if do not have embargo access, the direct links to the articles probably will not be accessible until then. However, you can click here for a brief description.

Also, Opher et al. have a paper ("The Orientation of the Local Interstellar Magnetic Field") with an accompanying Perspectives piece ("A Local Wiggle in the Turbulent Interstellar Magnetic Field") by Jokipii. Again, unless you have embargo access, click here for a brief description.
Go to the top of the page
 
+Quote Post
 
Start new topic
Replies
TheChemist
post Oct 14 2007, 09:47 AM
Post #2


Member
***

Group: Members
Posts: 524
Joined: 24-November 04
From: Heraklion, GR.
Member No.: 112



I don't know if this has been already mentioned, but there is a new Titan atmospheric photochemistry model published
in two papers in Planetary and Space Science, articles in press page. Apologies, this is a long and badly-formatted post.

The model article is :
--------------------------------------------------------------------------------------------------
Coupling photochemistry with haze formation in Titan's atmosphere. Part I: Model description
In Press, Accepted Manuscript, Available online 12 September 2007,
P.P. Lavvas, A. Coustenis and I.M. Vardavas
PDF (812 K)
--------------------------------------------------------------------------------------------------

The validation with Cassini Huygens data :

--------------------------------------------------------------------------------------------------
"Coupling photochemistry with haze formation in Titan's atmosphere. Part II: Results and validation with Cassini/Huygens data"
In Press, Accepted Manuscript, Available online 12 September 2007,
P.P. Lavvas, A. Coustenis and I.M. Vardavas
PDF (2433 K)
--------------------------------------------------------------------------------------------------

I think I can bend the rules and provide the abstracts rolleyes.gif (after all, they will be available to non-subscribers shortly)

--------------------------------------------------------------------------------------------------
Abstract Part I
We introduce a new 1D coupled Radiative / Convective - Photochemical - Microphysical model for a planetary atmosphere and apply it to Titan. The model incorporates detailed radiation transfer calculations for the description of the shortwave and longwave fluxes which provide the vertical structure of the radiation field and temperature profile. These are used for the generation of the photochemistry inside the atmosphere from the photolysis of Titan's main constituents, nitrogen (N2) and methane (CH4).
The resulting hydrocarbons and nitriles are used for the production of the haze precursors, whose evolution is described by the microphysical part of the model. The calculated aerosol and gas opacities are iteratively included in the radiation transfer calculations in order to investigate their effect on the resulting temperature profile and geometric albedo. The main purpose of this model is to help in the understanding of the missing link between the gas production and particle transformation in Titan's atmosphere. In this part, the basic physical mechanisms included in the model are described. The final results regarding the eddy mixing profile, the chemical composition and the role of the different haze precursors suggested in the literature are presented in Part II along with the sensitivity of the results to the molecular nitrogen photoinization scheme and the impact of galactic cosmic rays in the atmospheric chemistry.
--------------------------------------------------------------------------------------------------


--------------------------------------------------------------------------------------------------
Abstract Part II
"The new one-dimensional radiative-convective/photochemical/microphysical model described in Part I is applied to the study of Titan's atmospheric processes that lead to haze formation. Our model generates the haze structure from the gaseous species photochemistry. Model results are presented for the species vertical concentration profiles, haze formation and its radiative properties, vertical temperature/density profiles and geometric albedo. These are validated against Cassini/Huygens observations and other ground-based and space-borne measurements. The model reproduces well most of the latest measurements from the Cassini/Huygens instruments for the chemical composition of Titan's atmosphere and the vertical profiles of the observed species.
For the haze production we have included pathways that are based on pure hydrocarbons, pure nitriles and hydrocarbon/nitrile copolymers. From these, the nitrile and copolymer pathways provide the stronger contribution, in agreement with the results from the ACP instrument, which support the incorporation of nitrogen in the pyrolised haze structures. Our haze model reveals a new second major peak in the vertical profile of haze production rate between 500 and 900 km. This peak is produced by the copolymer family used and has important ramifications for the vertical atmospheric temperature profile and geometric albedo. In particular, the existence of this second peak determines the vertical profile of haze extinction.
Our model results have been compared with the DISR retrieved haze extinction profiles and are found to be in very good agreement. We have also incorporated in our model heterogeneous chemistry on the haze particles that converts atomic hydrogen to molecular hydrogen. The resultant H2 profile is closer to the INMS measurements, while the vertical profile of the diacetylene formed is found to be closer to that of the CIRS profile when this heterogenous chemistry is included."
--------------------------------------------------------------------------------------------------

This post has been edited by alan: Oct 14 2007, 03:18 PM
Reason for edit: improved formating
Go to the top of the page
 
+Quote Post
Webscientist
post Nov 30 2007, 09:12 AM
Post #3


Member
***

Group: Members
Posts: 100
Joined: 30-November 05
From: Antibes, France
Member No.: 594



A living mist?
Go to the top of the page
 
+Quote Post
ngunn
post Nov 30 2007, 10:44 AM
Post #4


Senior Member
****

Group: Members
Posts: 3516
Joined: 4-November 05
From: North Wales
Member No.: 542



QUOTE (Webscientist @ Nov 30 2007, 09:12 AM) *
A living mist?


Let's take that one head on. The formation of each haze particle is presumably a quasi-random cumulative process leading in one direction only - its eventual deposition on the surface of Titan. For anything remotely resembling life to get going you need a cyclic process where the outcome of one cycle alters the conditions in which the next cycle occurs, thereby affecting its outcome, and so on. It's not impossible to imagine such things happening on Titan, though even if there are I'm sure there would still be semantic disputes about the term 'life'. However IMHO haze particle formation is not such a process.

If you were speaking 'poetically' please forgive me for being a terrible pedant.
Go to the top of the page
 
+Quote Post

Posts in this topic
- AlexBlackwell   The Process of Tholin Formation in Titan's Upper Atmosphere   May 10 2007, 06:04 PM
- - AlexBlackwell   The embargo has been lifted and the papers are now...   May 10 2007, 08:33 PM
- - AlexBlackwell   Cassini spacecraft reveals evidence of tholin form...   May 10 2007, 11:57 PM
- - Littlebit   QUOTE Using measurements from a combination of mas...   May 11 2007, 02:42 PM
|- - Juramike   QUOTE (Littlebit @ May 11 2007, 10:42 AM)...   May 11 2007, 05:27 PM
- - AlexBlackwell   QUOTE (AlexBlackwell @ May 10 2007, 08:04...   May 23 2007, 07:17 PM
- - TheChemist   I don't know if this has been already mentione...   Oct 14 2007, 09:47 AM
|- - Webscientist   A living mist?   Nov 30 2007, 09:12 AM
|- - ngunn   QUOTE (Webscientist @ Nov 30 2007, 09:12 ...   Nov 30 2007, 10:44 AM
||- - marsbug   QUOTE (ngunn @ Nov 30 2007, 11:44 AM) Let...   Oct 13 2008, 03:17 PM
|- - Juramike   QUOTE (Webscientist @ Nov 30 2007, 04:12 ...   Nov 30 2007, 12:12 PM
- - ngunn   More on this topic: http://www.ucl.ac.uk/media/lib...   Nov 29 2007, 11:39 AM
- - TheChemist   Well, there is a lot of heterogeneous chemistry (s...   Nov 30 2007, 02:57 PM
- - marsbug   My apologies for resurrecting this thread but re-r...   Sep 22 2008, 09:37 AM
- - Juramike   (I think I'm gonna have to reread these full p...   Sep 22 2008, 12:09 PM
|- - marsbug   Thanks Mike! I've been doing some more res...   Sep 22 2008, 01:13 PM
- - TheChemist   The only NMR reference I can recall is in this Sag...   Sep 22 2008, 02:01 PM
- - marsbug   Hmmm, to throw a thought out at random, perhaps th...   Sep 22 2008, 06:19 PM
|- - Juramike   QUOTE (marsbug @ Sep 22 2008, 01:19 PM) T...   Sep 22 2008, 06:35 PM
- - Juramike   Found the recent NMR paper (and it's free)...   Sep 23 2008, 03:22 AM
- - ngunn   New CHARM presentation on this topic now: http://s...   Oct 28 2008, 02:09 PM


Reply to this topicStart new topic

 



RSS Lo-Fi Version Time is now: 15th December 2024 - 11:06 PM
RULES AND GUIDELINES
Please read the Forum Rules and Guidelines before posting.

IMAGE COPYRIGHT
Images posted on UnmannedSpaceflight.com may be copyrighted. Do not reproduce without permission. Read here for further information on space images and copyright.

OPINIONS AND MODERATION
Opinions expressed on UnmannedSpaceflight.com are those of the individual posters and do not necessarily reflect the opinions of UnmannedSpaceflight.com or The Planetary Society. The all-volunteer UnmannedSpaceflight.com moderation team is wholly independent of The Planetary Society. The Planetary Society has no influence over decisions made by the UnmannedSpaceflight.com moderators.
SUPPORT THE FORUM
Unmannedspaceflight.com is funded by the Planetary Society. Please consider supporting our work and many other projects by donating to the Society or becoming a member.