QUOTE (nprev @ Sep 12 2007, 10:26 PM)

Okay, question...does anybody know how complex liquid hydrocarbons might behave in a cold vacuum? (Lookin' at you, Juramike...)
Some "complex" hydrocarbons may actually be volatile.
One way to degas (and purify) benzene:
1) Put benzene in a stopcocked flask connected to a 3 way tube with stopcock and connected to a vacuum line and also connected to another stopcocked flask (the receiver)
2) Freeze it (-78 C in dry ice/acetone bath is an easy way to do it in the lab, even though benzene melts at 5 C)
3) Open stopcocks to vacuum. Pull vacuum on entire system
4) Close stopcock to vacuum.
5) Remove cold bath under benzene-containing flask.
6) Move cold bath to empty flask.
7) After material transfers over to receiver flask, close stopcock, let benzene thaw. (You can now transfer flask into a drybox while still under vacuum, or put benzene under argon for air-sensitive reactions.)
Benzene sublimes in the vacuum, then recondenses into the cooled flask.
Wild idea, and not to well thought out on my part, but I wonder if it is possible if some of the ices we are seeing may be organic ices? Some might be volatile enough to transfer around. And some might even turn dark after enough exposure to light (UV photochemistry).
This could put a whole new level of complexity into the system (nicely described in the graphic by SFJCody
here), with a thin coating of white stuff (ice), and a thing coating of white/dark stuff (organic ices) being mobile.
Is there any spectral data out there that could nip this hypothesis in the bud?
-Mike